Comments
on
Department of Energy
Idaho National Engineering and Environmental Laboratory
Idaho Chemical Processing Plant
Proposed Cleanup Plan
Submitted on Behalf of the
Environmental Defense Institute
by
Chuck Broscious
November 19, 1998
The US Department of Energy (DOE) Idaho Chemical Processing Plant (ICPP) proposed plan is
an improvement over the 6/98 draft version. Providing drafts of proposed plans is a
constructive process that extends the comment period beyond the traditional "decide,
announce, defend" mode formerly used by DOE. One of the significant changes is the
shifting of the ICPP high-level waste tank farm contaminated soils over into a separate
operable unit to be evaluated under a new remedial investigation/feasibility study. This
shift occurred primarily because the Environmental Defense Institute using DOE's own
sample data showed that the draft plan did not meet applicable or relevant and appropriate
requirements (ARAR). DOE failed to correctly classify the waste that the plan addressed.
Two of the contaminated soil sites (CPP-28 & CPP-79) have transuranic (TRU) elements
that cumulatively exceed the TRU definition of 100 nano curies per gram. (1)
This waste must go to an Nuclear Regulatory (NRC)/ Environmental Protection Agency (EPA)
approved geologic repository specifically permitted for TRU waste. Since this
contamination resulted from over 100 leaks in the high-level liquid and calcine waste
pipes, and acknowledged in DOE's work plan document as high-level waste, a legitimate case
can be made that it still is high-level waste and subject to Nuclear Regulatory Commission
disposal regulations. (2) Also see Natural Resources
Defense Council petition to Nuclear Regulatory Commission July 28, 1998 that legally
challenges DOE's attempt to change high-level waste to "incidental" low-level
waste. The high level waste tank farm soils are included in these comments because it is
uncertain how much if any public comment will be solicited prior to a record of decision.
The fact that DOE failed to correctly categorize the waste in the SFE-20 Hot Waste Tank as
TRU in this plan is indicative that the agency will also try to circumvent legal
requirements in the Tank Soils cleanup plans.
Additionally, DOE failed to correctly catagorize the other waste as mixed low-level (MLLW) which requires either approved treatment or disposal in a permitted Resource Conservation Recovery Act (RCRA) Subtitle C hazardous waste dump.(3) Neither of which the DOE initially planed to do until the Environmental Defense Institute exposed the lack of regulatory compliance. Now DOE plans to build a compliant RCRA Subtitle C hazardous waste dump (called the INEEL CERCLA Disposal Facility or ICDF) near the current ICPP percolation ponds. There remain major uncertainties related to the siting location and the waste acceptance criteria that will be discussed later in these comments.
The Plan notes that the CPP-37gravel pits and CPP-66 Fly-ash Pit (which both sound innocuous)will be closed under Idaho Solid Waste Rules (IDAPA 16.01.06). However, the Site Treatment Plan and the Remedial Investigation/ Feasibility Study (RI/FS) show the Gravel Pits as a mixed waste discharge site with a volume of 84,393 cubic meters of waste dumped in the two pits. The RI/FS lists seven radionuclides in pit #1 and eight radionuclides in pit #2. The RI/FS lists the Fly-ash Pit with four radionuclides and RCRA listed hazardous waste contaminates. [INEL-95/0056@3-22] Similarly, DOE wants to close the CPP-65 Sewage Lagoon under Idaho Waste Water Land Application Rules, yet the RI/FS lists the site as having contaminates in the lagoon waste water. [3-22] These waste sites must be remediated under the same RCRA requirements as the other mixed hazardous/radioactive waste sites.
The chart below cites sampling data collected by DOE and published in its 1995 ICPP Remedial Investigation / Feasibility Study (RI/FS) and this data shows specifically how the waste meets mixed low level waste (MLLW) and TRU criteria. DOE's own Site Treatment Plan Congressionally mandated by the Federal Facility Compliance Act further shows specifically the MLLW classification for these contaminated sites.
The "Other Surface Soils (Group 3)" preferred alternative 4-A is to excavate contaminated surface soils to a depth of ten feet. A review of the RI/FS Appendix C borehole sample data for Strontium-90 and Cesium-137 shows that DOE's arbitrary ten foot depth would leave most of the contamination in place because it goes down generally to thirty feet. Unfortunately, there is not sample data for all of the sites in this group (and there should be), but at least four sites need to go to around 15 feet and four sites need to go to about 30 feet in order to recover the bulk of the contamination. Stopping at ten feet is not acceptable and is not supported by the data. To cite an example, CPP-36 has 50,000 pCi/g of Sr-90 and 200,000 pCi/g of Cs-137 at fifteen feet of depth. [INEL-95/0056] A fixed health base cleanup standard is needed and then require DOE keep digging until the samples show that the contaminates do not exceed the standard.
After years of pressure from the Environmental Defense Institute and other public interest groups, the state and EPA regulators finally forced DOE to construct an onsite RCRA/NRC compliant Subtitle C hazardous/radioactive mixed low-level waste (MLLW) dump at INEEL. In previous "cleanup' actions DOE was just consolidating its MLLW into old waste percolation ponds and covering it over. The unlined Warm Waste Percolation Pond at the INEEL Test Reactor Area, Test Area North, and Argonne-West are examples of this illegal dumping practice. The RCRA Subtitle C dumps have double liners, leachate detection/collection systems, and impermeable caps. The reason these RCRA laws are on the books is because previous disposal practices resulted in migration of the waste into underlying groundwater. Water sample data at the ICPP already shows massive migration of pollution into the groundwater. Despite this encouraging commitment to meet regulatory requirements and construct a RCRA Subtitle C dump (called the INEEL CERCLA Disposal Facility [ICDF]), the choice to locate it at the ICPP is misguided.
The reason why locating the ICDF at the ICPP - especially underground - is because the northern part of the ICPP lies in the 100 flood plain of the Big Lost River. DOE's plan is to locate the ICDF near the ICPP percolation ponds which are immediately south of the perimeter fence. The ICPP as a whole is about as flat as a table top. The US Geological Survey (USGS) released a study this year (1998) acknowledging that the northern half of the ICPP would be flooded in a peak 100-year flood.(4) USGS estimated that the ICPP would be under several feet of moving water and the Big Lost flow rate at 7,260 cubic feet per second. The detailed report map shows the northern half of the ICPP would be under as much as four feet of water. "This peak flow was routed down stream [of the Big Lost River] as if the INEEL diversion dam did not exist. On the basis of a structural analysis of the INEEL diversion dam (U.S. Army Corps of Engineers) the dam was assumed incapable of retaining high flows. The Corps indicated that the diversion dam could fail if flows were to exceed 6,000 cubic feet per second."(5) Since the radioactive waste will be extremely hazardous for tens of thousands of years, a conservative risk assessment would consider a 500-year flood rates at 9,680 cubic feet per second (34% greater flow rate than 100 year).(6) This 500-year flood would inundate the ICPP and surrounding area. Cascading events should also be considered. A 500-Year flood plus failure of Mackay Dam (built in 1917) resulting in estimated flows of 9,700 + 54,000 cubic feet per second respectively. Failure of Mackey Dam is non-speculative in view of the recent failure of the Teton Dam of similar construction. USGS did not consider cascading events but noted previous studies showing that failure of Mackay Dam alone would result in 6 feet of water at the INEEL Radioactive Waste Management Complex.(7) Building dams around the ICDF as was done at the RWMC is not an acceptable answer because lateral water migration will go under the dams and local precipitation will be held in exacerbating the leachate conditions. Dams by definition are only functional if there is regular maintenance which cannot be assumed once DOE ends institutional control of INEEL. Dumping the waste on top of the ground and mounding the cover over it will result in the cap eroding over the long-term which again is unacceptable. DOE must designate another location for the ICDF that is not near a flood plain and preferably not over the aquifer. DOE's own study has identified at least two such sites where the Lemi Range meets the Snake River Plain. (8)
Nuclear Regulatory Commission restrictions prohibiting citing radioactive waste disposal dumps on 100 year flood plains must be observed. [ NRC 10 CFR ss 61.50] The reason for these restrictions is because the flood water will leach the contaminates out of the waste and flush the pollution more rapidly into the aquifer. Since these wastes will remain toxic for tens of thousands of years, they must be disposed of responsibly in a safe permanent repository. These issues must be kept in mind also with respect to the ICPP high-level waste tanks that are some forty feet underground as well as the underground spent reactor fuel storage and calcine storage bins. Water acts as a moderator and if the underground spent fuel vaults are flooded, it could cause a criticality. All of these underground high-level waste sites are extremely vulnerable. Former ICPP workers recall stacking sandbags six feet high around the plant during a Spring flood about ten years ago.
The ICDF Engineering Design and Waste Acceptance Criteria (WAC) must be developed with public involvement through a free and open discussion. Only un-containerized wastes that can be compacted during placement should be allowed so as to minimize subsidence caused by container decomposition. Biodegradable, VOC, collapsible, soluble, TRU, or Greater than Class C Low-level, and Alpha-low-level waste must also be excluded from the ICDF dump and sent off-site. Prior to completing the ICDF Title II Design, workshops should be convened for stakeholders to comment on the proposal. Waste Acceptance Criteria maximum contaminate concentration levels must be determined from waste sampling prior to being mixed with any stabilizing materials. In other words, "dilution is not the solution to pollution".
The following table lists a sampling of the contaminated sites at the ICPP. The table shows the contaminate, the concentration of the contaminates based on DOE's own sampling data, and a reference for where the information was obtained (see end of chart). The Tank Farm Soils are included because of the uncertainty of public comment availability if this waste is included in the High-Level Waste Environmental Impact Statement.
ICPP Site | Contaminate | Concentration | Reference |
Tank Farm Soils | Group 1 | ||
CPP-15 Solvent Burner Tank Leaks CPP-605 3 R/hr |
Cs-137 Pu-238 Pu-239/240 Tc-99 |
pCi/g 586,000 4,570 825 36 |
No Hazardous Materials sampling Inadequate info (B) @ 37 (C) 11-4 |
CPP-20 CPP-604 Unloading Area |
STP Listed MLLW Cs-137 |
pC/g 88 |
No Hazardous Materials sampling Inadequate info (A) 2-120 (D) 2-4 Vol. VII |
CPP-25 Leak between WC-119 WL-102 |
STP Listed MLLW | No Hazardous Materials sampling Inadequate info (A) 2-120 |
|
CPP-26 Steam Flush Explosion HL Tank Lines 13 acres contaminated 50,000 c/m beta/gamma |
Sr-90 Cs-137 |
pCi/g 15,800 6,730 |
No Hazardous Materials sampling Inadequate info (A) 2-120 (C) 10-6 Vol IV |
CPP-27 CPP-33 WL-102 Tank Line Leak 30 R/hr 300 gallons 1,000 curies 50,000 cpm |
Cs-137 Sr-90 |
pCi/g 1,370 506 |
No Hazardous Materials sampling Inadequate info (A) 2-125 (B) 35 +38 (D) 2-4 Vol VII |
CPP-28
South WM-181 3,629 gallons HLLW Leaked containing 46,400 Ci combined with CPP-79
400 R/hr |
Tritium Co-60 Sr-90 Cs-134 Cs-137 Pu-238* Pu-239 Pu-240 Pu-241 Am-241 Pu-242* U-234* Total TRU |
pCi/g 25,000 23,000 57,000,000 76,000 100,000,000 276,000 13,000 12,000 1,100,000 1,500,000 32 21 2,901,053 |
Exceeds TRU Waste = 100,000 pCi/g or 100 nCi/g
Requires deep geologic burial
(A) 2-121 (C) 10-8 (C) F5-25 Vol V (C) H-9 Vol VI |
CPP-31 South of WM-183 14,000 gallon HLLW leak Containing 40,988 Ci Released 10 R/hr |
Cs-137 Co-60 Sr-90 Cs-137 Eu-154 U-235 Pu-239 Pu-240 Mercuric nitrate Nitric acid |
pCi/g 899,000 336 710,000 2,190,000 2,750 9,000 1,100 1,100 |
No Hazardous Materials sampling Inadequate info (A) 2-121 (C) 10-13 Vol IV (C) H-14 Vol VI (B) 37 (D) 2-4 Vol VII (C) F5-29 Vol V |
CPP-32 HLLW above ground pipe leak Valve Box B-4 2 r/hr |
Cs-137 Sr-90 |
pCi/g 277 278 |
No Hazardous Materials sampling Inadequate info (A) 2-125 (B) 37 (C) 10-15 Vol IV |
CPP-58 PEW 20,000 Gallon Leak |
Cs-137 Sr-90 |
pCi/g 63.6 95.6 |
(A) 2-133 (C) 11-10 |
CPP-79 HLLW from WCF 2,500 gallons
Near Valve Box A-2 400 R/hr
46,400 Curies when combined with CPP-28 |
Gross alpha Sr-90 Cs-137 Eu-154 Am-241 Pu-238 Pu-239 Pu-241 U-234 Total TRU |
pCi/g 809,000 56,800,000 102,000,000 565,000 16,600 276,000 1,050,000 89,900 55 382,555 |
Exceeds TRU Waste = 100,000 pCi/g or 100 nCi/g Requires deep geologic burial (A) 2-123 (C) 10-17 Vol IV (D) 2-4 Part B Vol VII (C) H-9 Vol VI |
Other Surface | Soil Sites | Group 3 | |
CPP-91 | Am-241 Cs-137 Eu-154 Sr-90 |
pCi/g 763 1,100,000 5,040 56,700 |
No Hazardous Materials sampling Inadequate info (A) 2-137 (D) 2-4 Vol VII |
CPP-13 Calcine HLW from CPP-633 Contaminated 300 sq. ft. |
Zirconium Cs-137 Sr-90 |
pCi/g 14.3 4,630 4,180 |
No Hazardous Materials sampling Inadequate info (A) 2-124 (B) 37 (C) 19-4 |
CPP-36 Transfer Leak 750 gallons containing 8.44 curies and 20 r/hr |
STP Listed MLLW Sr-90 Cs-137 Pu-239 Am-241 Pu-238 |
pCi/g 139,750 5,174,400 320 760 8,200 |
(A) 2-126 (C) 12-7 RCRA waste |
CPP-35 WCF Calcine Vessel Decon Leak CPP-633 10 gallons 10 Curies |
STP Listed MLLW Sr-90 Cs-137 Eu-154 Pu-238 Hg |
pCi/g or mg/kg 3,240 8,640 20 17 5.5 |
Mercury likely exceeds LDR's TCLP .025 mg/l
RCRA waste (A) 2-125 (C) 12-4 |
CPP-93 Calcine Trench |
Aluminum Mercury |
mg/kg 120,000 140 |
Mercury likely exceeds LDR's TCLP .025 mg/l (A) 2-137 (C) 26-4 |
CPP-92 1500 2x4x8 boxes |
STP Listed MLLW Mercury Cs-137 Sr-90 Pu-238 Pu-239/240 |
mg/kg 10.4 7,730 10,800 259 24.7 |
RCRA Waste Mercury likely exceeds LDR's TCLP .025 mg/l (A) 2-137 (C) 25-2 |
CPP-34 Rad Soil Dump >30 mr/hr 110.23 Ci Released |
Sr-90 Cs-137 Lead U-234/238 Np-237 Pu-238 Mercury Silver Bis- (2 ethlhexyl) Phthalate |
pCi/g or mg/kg 6,000 2,000 132 5.3 0.7 5.1 |
Likely exceeds TCLP Mercury 0.75 mg/l RCRA Waste (A) 2-119 (B) 36 (C) 18-3 |
CPP-14 Sewage Plant Two Imhoff Tanks |
Arochlors (PCB) Cs-137 U-234 U-238 |
mg/kg or pCi/g 23 6.21 6.89 52.1 |
Exceeds LDR for PCB @ 10 mg/kg RCRA Waste (A) 2-118 (C) 17-5 |
CPP-44 Grease Pit |
Chromium Lead Mercury |
mg/kg 1,540 163 5 |
Likely exceeds LDR's TCLP Chrom.0.6mg/l Lead 0.75 mg/l Mercury 0.025 mg/l RCRA Waste (A) 2-131 |
CPP-55 Mercury Contaminate CPP-T-15 |
Chromium (total) Mercury |
mg/kg 130 5.2 |
Likely exceeds LDR's TCLP Chromium 0.6mg/l Mercury 0.025 mg/l RCRA Waste (A) 2-115 |
CPP-67 Percolation ponds |
Cs-137 Pu-238 Pu-239-240 Sr-90 |
pCi/g 93.6 13 2.07 16.3 |
Inadequate hazardous waste sampling (A) 2-117 (C) 16-5 (D) 2-4 Vol VII |
Soils Under |
Buildings | Group 2 | |
CPP-02 CPP-603 French Drain 493 Curies Released |
4,777,688 gallons | No Hazardous Materials sampling Inadequate info (A) 2-127 (C) F5-21 Vol V |
|
CPP-87 CPP-604 Vapor Off-gas blower PEW Pump Cell |
Co-60 Cs-134 Cs-137 |
pCi/L 70,740 4,018 330,4180 |
No Hazardous Materials sampling Inadequate info
(A) 2-136 |
CPP-89 Tunnel between CPP-604 & 605 |
Mercury Cs-137 Pu-238 Pu-239/240 Sr-90 |
pCi/g or mg/kg 10.4 7,730 259 24.7 10,800 |
Lead likely exceeds LDR's TCLP Mercury 0.025 mg/l RCRA Waste (A) 2-136 (C) 5-73 |
CPP-80 CPP-601 Vent Tunnel Drain 550 Curies Released |
Cs-137 Sr-90 |
pCi/g 86,300 85,600 metal contaminates |
No Sampling Inadequate info (A) 2-133 (C) 9-11 |
CPP-01 CPP-603 Settling Basin and dry wells # SW-048 & CPP-303 |
Cs-137 Sr-90 Co-60 Eu-154/155 |
pCi/g 46,000 4,850 322 35,000 |
No Hazardous Materials sampling Inadequate info (C) 13-6 (A) 2-127 |
CPP-03 Open Storage Area |
Cs-137 Eu-152 Sr-90 |
pCi/g 65.1 2.13 43.9 |
No Hazardous Materials sampling Inadequate info
(A) 2-127 |
CPP-04 CPP-05
CPP-603 soil around settling tank |
Cs-134 Cs-137 Ce-144 Co-60 Eu-152 Eu-154 Eu-155 |
pCi/g 1,450 26,500 2,390 2,390 35,000 35,000 7,600 |
No Hazardous Materials sampling Inadequate info
(A) 2-127 (D) 2-4 Volume VII |
CPP-08 CPP-09 Open near CPP-603 |
Cs-137 | 1,080 pCi/g | No Hazardous Materials sampling Inadequate info (A) 2-128 (D) 2-4 Vol VII |
CPP-10 800 gallon leak beside CPP-603 20,000 cpm |
Cs-137 | 1,190 pCi/g | No Hazardous Materials sampling Inadequate info (A) 2-127 (C) 11-13 (D) 2-4 Volume VII |
CPP-11 SFE-106 Tank 500 gallon leak |
Cs-137 |
pCi/g 72.7 |
No haz mat. sampling (C) 13-14 (D) 2-4 Vol VII |
CPP-19 CPP-603 to CPP-604 3,500 Gallon Line Leak |
Cs-137 Co-60 Eu-152 Eu-154 Eu-155 Pu-239 Sr-90 |
pCi/g 408,000 21,600 87,600 53,500 9,620 141 125,000 |
Inadequate Hazardous Materials sampling Inadequate info
(A) 2-129 (C) 21-4 (D) 2-5 Volume VII |
The ICPP Remedial Investigation/Feasibility Study lists 100 chemical/radiological release sites. Of the 100 release sites, 13 are related to the tank farm. The estimate of radioactivity in decayed values in the surface soils within the ICPP compound listed above is 89,569 curies plus 22,200 curies released to the aquifer.
DOE's Plan discounts the Perched Water as "No risk because perched water is not capable of sustaining a pumping rate needed for future domestic water supplies; therefore it is not a source of potable water." Yet in ICPP Plan Alternative 3 (not the preferred alternative), DOE acknowledges a perched water pump/treat rate of 46 million gallons over 25 years. Applying simple arithmetic that works out to a daily pumping rate of 5,041 gallons per day which is likely adequate to sustain over ten households. Therefore, DOE must include a future residential exposure scenario that would disqualify the preferred alterative 2 which is basically doing nothing except reduce the recharge rate to the perched water. The table below shows a select list of contaminates found in perched water. Comparing the concentration level of the sample to the regulatory limit or maximum concentration level (MCL) for drinking water, one can see the severity of the pollution problem. DOE and the state and EPA regulators once again have withheld this essential information from the public by not stating it in the proposed plan. In order to make informed decisions on these cleanup plans, the public requires adequate and accurate information which currently is absent.
Perched Water at ICPP
Contaminate | Concentration (mg/l) (pCi/l) | EPA Std. (MCL) | Reference page number |
Gross Alpha | 7,290 | 15 | (A) 2-155 |
Gross Beta | 925,000 | 8 | (A) 2-160 |
Tritium | 75,500 | 20,000 | (A) 2-162 |
Strontium-90 | 516,000 | 8 | (A) 2-160 |
Iodine-129 | 3.82 | 1 | (C) 4-47 |
Cadmium | 0.012 | 0.005 | (A) 2-155 |
Chromium | 1.6 | 0.1 | (A) 2-184 |
Lead | 0.0651 | 0.05 | (A) 2-155 |
Manganese | 0.397 | 0.05 | (A) 2-155 |
Thallium | 0.0052 | 0.002 | (A) 2-161 |
Iron | 15 | 0.3 | (A) 2-180 |
(A) INEL-95/0056 (C) DOE/ID-10534 Volume IV
The perched water preferred alternative 2 alone does not meet
regulatory requirements, however when combined with alternative 3 (pump and treat) it will
partially meet the requirements with the following exception. In order to reduce the
recharge to the perched water, the existing ICPP percolation ponds will be taken out of
service and replaced with new "like for like" percolation ponds not over the
existing perched water. This is a good an example of rubber stamp regulators. The
contamination of the groundwater currently is largely the result of using unlined
percolation ponds to dispose of process waste. The very fact that the current percolation
ponds are still in use today is a clear and undeniable statement of DOE's lack of
conscience. It is an outrage for DOE to continue this polluting of Idaho's most valuable
resource.
The Plan's "human health baseline risk assessment summary" uses maximum contaminate levels to determine risk level for each of the contaminate groups. Again, DOE is not using "maximum" contaminate data. For instance, the Snake River Aquifer risk assessment strontium-90 level used by DOE is 8.1 yet DOE's own sampling data in the Remedial Investigation Feasibility Study (RI/FS) shows 14 aquifer monitoring wells that exceed the MCL including USGS-047 with strontium-90 levels over 60 pCi/L. [INEL-95/0056 @ D-19] DOE additionally fails to acknowledge aquifer tritium contamination in excess of the MCL's. DOE's use of arbitrarily low or averaged sample data results in unreliable and non-conservative risk assessments. This cooking of the numbers is not an anomaly but unfortunately the rule as opposed to the exception. See EDI comments on previous cleanup plans. Snake River Plain Aquifer (Group 5) should be remediated with a pump and treat (alternative 3) for the same reasons the perched water should be removed and treated.
None of the SFE-20 Hot Waste Tank System (Group 7)(CPP-69) cleanup alternatives offered in the ICPP plan meet regulatory requirements. Once again, DOE fails to correctly classify the waste in SFE-20 tank in a blatant attempt to circumvent regulatory requirements. The Remedial Investigation/ Feasibility Study sample data of the tank (see table below) shows clearly that the tank contents (liquid and sludge) as well as the tank concrete vault contents meet the definition of mixed transuranic (TRU) waste, and by regulatory definition, it must go to a deep geologic repository. Grouting (mixing with cement) as proposed by DOE, is a throughly discredited disposal method - tried and failed at Hanford. The bottom line is DOE cannot legally dump transuranic waste at INEEL. In fact, the only transuranic waste repository in the United States under consideration is the Waste Isolation Pilot Project in New Mexico. However, the State of New Mexico is uncertain that WIPP can meet RCRA permit criteria.
SFE-20 Hot Waste Tank System Group 7 (CPP-69)
Contaminate | Concentration | Notes/Reference |
Tank Liquid (400 gallons) Cs-134 Cs-137 Sr-90 Plutonium total Co-60 Sb-125 |
pCi/L 7,800 2,100,000 9,700,000 18,000,000 74,000 73,000 |
CPP-512 CPP-603 Waste Tank Fuel Cutting Facility (C) page 9-9 Vol IV (D) page I-5 Vol VII
TRU waste |
Tank Sediments (55 gallons) Co-60 Cs-137 Cs-134 Eu-152 Eu-154 Sr-90 Plutonium total Uranium total |
pCi/g 330,000 55,400,000 160,000 140,000 120,000 4,700,000,000 94,000 84,000 |
Exceeds TRU Waste = 100,000 pCi/g or 100 nCi/g Plutonium + Uranium
|
Tank Vault Liquid Cs-137 Co-60 Sr-90 Plutonium total |
pCi/L 250,000,000 110,000 170,000,000 100,000 |
Likely TRU Waste * |
Tank Vault Sediments Co-60 Cs-137 Cs-134 Eu-152 Eu-154 Eu-155 Sr-90 Plutonium total |
pCi/g 22,000 8,920,000 11,000 150,000 130,000 47,000 1,720,000 79,200 |
Likely TRU Waste |
Tank Pump Pit Sediment Co-60 Cs-137 Cs-134 Eu-152 Eu-154 Eu-155 Sb-125 Sr-90 Plutonium total |
pCi/g 24,000 2,390,000 13,000 57,000 46,000 21,000 47,000 5,900,000 3,010 |
|
Tank Pump Pit Liquid Cs-137 |
pCi/L 76,000 |
|
Site Treatment Plan lists as Mixed Cadmium Mercury |
mg/kg 260 |
Likely Exceeds LDR TCLP Cadmium 0.11 mg/l Mercury 0.025 mg/l A.4-136 |
* The assumption is that if a ml of water weights a gram, the sediments containing heavy metals will weigh considerably more than plain water and therefore the sediment will meet the transuranic definition of 100,000 pCi/g
References
(A) Waste Area Group 3 Comprehensive Remedial Investigation / Feasibility Study Work Plan (Final) Volume I, August 1995, INEL-95/0056, Lockheed Idaho Technologies Company
(B) Department of Energy Idaho Operations Office, Session 1 Presentation Scope of Comprehensive RI/FR and ICPP Background, Talley Jenkins, Session 2 Scott Reno DEQ, Session 3 Howard Orlean EPA, January 17, 1996
(C) Comprehensive Remedial Investigation/ Feasibility Study for the Idaho Chemical Processing Plant Operational Unit 3-13 at Idaho National Engineering Laboratory Part A RI/BRA Report (Final) US Department of Energy Idaho Operations Office, November 1997, DOE/ID-10534 Volume IV, V, and VI
(D) Comprehensive RI/FS for the Idaho Chemical Processing Plant OU-3-13 at INEEL - Part B, FS Report Final Volume VII, DOE/ID-10572, November 1997
STP: Idaho National Engineering Laboratory Proposed Site Treatment Plan, March 1995, DOE/ID-10493, US Department of Energy Idaho Operations Office
Federal Register, Tuesday May 26, 1998, Part-II, Environmental Protection Agency, 40 CFR Parts 148, 261, 266, 268, and 271, Land Disposal Restrictions Phase IV, Final Rule
Acronyms:
LDR: Land Disposal Restrictions (RCRA) TCLP: Toxic Contaminate Leach Procedure
RCRA: Resource Conservation Compliance Act MLW: Mixed Low-Level Waste
UTS: Universal Treatment Standards under RCRA
1. Transuranic waste is defined as waste containing more than 100 nanocuries (100,000 pico curies) of alpha-emitting transuranic isotopes (atomic numbers greater than natural uranium) with half-lives greater than 20 years per gram of waste. Plutonium is a transuranic isotope.
2. Nuclear Regulatory Commission 10 Code of Federal Regulations ss 60 and 61 defines high-level waste as (1) irradiated reactor fuel, (2) liquid wastes resulting from the operation of the first cycle solvent extraction system, or equivalent, and the concentrated wastes from subsequent extraction cycles, or equivalent, in a facility for reprocessing irradiated reactor fuel, and (3) solids into which such liquid wastes have been converted (ie. calcine).
3. Land disposal restrictions (LDR) limitations on land disposal or storage of waste set forth in Idaho Code Title 39 Chapters 44 and 58 and the Rules, Regulations, and Standards for Hazardous Waste, IDAPA ss16.01.05011; Resource Conservation Recovery Act (RCRA) 42 U.S.Code ss 6924; and 40 Code of Federal Regulations (CFR) 268.
4. Preliminary Water-Surface Elevations and Boundary of the 100 Year Peak Flow in the Big Lost River at the Idaho National Engineering and Environmental Laboratory, Idaho, US Geological Survey, Water-resources Investigations report 98-4065, DOE/ID-22148
5. DOE/ID-22148, page 8
6. Estimated 100 Year Peak Flows and Flow Volumes in the Big Lost River and Birch Creek at the Idaho National Engineering Laboratory, U.S. Geological Survey, Water Resources Investigations Report 96-4163, page 11 shows flow rates for 5-year, 10-year, 100-year, and 500-year floods
7. DOE/ID-22148, page 6
8. Moriarty, T. P., Feasibility of Locating Dry Storage of Spent Nuclear Fuel on Idaho National Engineering Laboratory Land at a Site That Does Not Overlie the Snake River Aquifer, November 1995